Export citation

Show simple item record

dc.contributor.authorMatthias Westerhausen (Ed.)*
dc.date.accessioned2021-02-12T02:42:34Z
dc.date.available2021-02-12T02:42:34Z
dc.date.issued2017*
dc.date.submitted2017-12-06 12:48:40*
dc.identifier24752*
dc.identifier.urihttps://directory.doabooks.org/handle/20.500.12854/58746
dc.description.abstractThe coordination chemistry of the s-block metals spans diverse fields, ranging from shielded coordination compounds over hydride to organometallic complexes for diverse applications. New developments pertain, not only to the lithium and magnesium chemistry with inspiring examples, such as heterobimetallic or heteroleptic complexes with special reactivity patterns, but the heavy s-block metals have progressively gained attention in various fields. Subvalent magnesium(I) derivatives are increasingly being used for reduction reactions, turbo-Grignard reagents show enhanced reactivity and tolerance toward functional groups, hydrides act as hydrogen storage materials, heavy Grignard reagents are available by straight forward procedures—just to name a few examples. Quantum chemical calculations deal with unique bonding situations and the relevance of d-orbital participation has been discussed to understand structure-reactivity relationships. Especially the complexes of the heavy alkaline earth metals are catalytically active in diverse reactions, promoting hydrofunctionalization reactions and Lewis acid catalysis. This Special Issue aims to highlight the structural and chemical diversity of s-block metal complexes, as well as the broad field of applications.*
dc.languageEnglish*
dc.subjectQD1-999*
dc.subject.others-block metal coordination compounds*
dc.subject.otherGrignard-type reagents*
dc.subject.otherLochmann-Schlosser bases*
dc.subject.otherheterobimetallic complexes*
dc.subject.others-block metal-mediated catalysis*
dc.subject.otherbonding in s-block complexes*
dc.titles-Block Metal Complexes*
dc.typebook
oapen.relation.isPublishedBy46cabcaa-dd94-4bfe-87b4-55023c1b36d0*
virtual.oapen_relation_isPublishedBy.publisher_nameMDPI - Multidisciplinary Digital Publishing Institute
virtual.oapen_relation_isPublishedBy.publisher_websitewww.mdpi.com/books
oapen.relation.isbn9783038425892*
oapen.relation.isbn9783038425908*
oapen.pagesVIII, 146*
oapen.edition1st*


Files in this item

FilesSizeFormatView

There are no files associated with this item.

This item appears in the following Collection(s)

Show simple item record

https://creativecommons.org/licenses/by-nc-nd/4.0/
Except where otherwise noted, this item's license is described as https://creativecommons.org/licenses/by-nc-nd/4.0/