Charakterisierung und Modellentwicklung von Natur und Funktionalität der Kathoden/Elektrolyt-Grenzfläche von Hochtemperatur-Brennstoffzellen (SOFC)
Abstract
Solid oxide fuel cells (SOFC) achieve high efficiencies, the lower the internal electrochemical losses are. This work investigates insulating secondary phases at the cathode/electrolyte interface that are formed during fabrication. Full cells and model systems are electrochemically characterized, analyzed by electron microscopy and reconstructed by tomography. A FEM model reveals performance limiting factors. As a result, an optimized production routine is proposed.
Keywords
elektrochemische Impedanzspektroskopie; electrochemical impedance spectroscopy; FEM-Modellierung; korrelative Tomographie; secondary phase identification; solid oxide fuel cell (SOFC); Zweitphasenidentifikation; correlative tomography; FEM modeling; Hochtemperatur-Brennstoffzelle (SOFC)ISBN
9783731508618Publisher
KIT Scientific PublishingPublisher website
http://www.ksp.kit.edu/Publication date and place
2019Series
Schriften des Instituts für Angewandte Materialien - Werkstoffe der Elektrotechnik, Karlsruher Institut für Technologie / Institut für Angewandte Materialien - Werkstoffe der Elektrotechnik,Classification
Technology: general issues